Square Wave Anodic Stripping Voltammetry Determination of Arsenic (III) onto Carbon Electrodes by Means of Co-deposition with Silver

Authors

  • Sandra Perla Méndez Cortés Universidad Autónoma del Estado de Hidalgo, Instituto de Ciencias Básicas e Ingeniería, Área Académica de Química
  • Carlos Andrés Galán Vidal Universidad Autónoma del Estado de Hidalgo, Instituto de Ciencias Básicas e Ingeniería, Área Académica de Química
  • José Antonio Rodríguez Ávila Universidad Autónoma del Estado de Hidalgo, Instituto de Ciencias Básicas e Ingeniería, Área Académica de Química
  • Giaan Arturo Álvarez Romero Universidad Autónoma del Estado de Hidalgo, Instituto de Ciencias Básicas e Ingeniería, Área Académica de Química
  • María Elena Páez Hernández Universidad Autónoma del Estado de Hidalgo, Instituto de Ciencias Básicas e Ingeniería, Área Académica de Química

DOI:

https://doi.org/10.29356/jmcs.v62i2.430

Keywords:

arsenic, square wave anodic stripping voltammetry, silver co-deposition, carbon screen printed electrode, glassy carbon electrode

Abstract

In the present study an electrochemical assay for the detection of arsenic (III) by means of square wave anodic stripping voltammetry with co-deposition of silver at screen printed and glassy carbon electrodes is presented. This methodology shows a good behavior in presence of dissolved oxygen with appropriate detection limits to monitoring the water quality according to the guidelines values. The evaluation of most important interfering ions (Cl-, Hg2+, Pb2+ and Cu2+) is also described. The proposed analytical strategy demonstrated to be suitable for decentralized arsenic analysis and can be easily integrated to portable instrumentation commercially available.

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References

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Published

2018-06-06

Issue

Vol. 62 No. 2 (2018): Special Issue on “Modern Analytical Chemistry in Interdisciplinary Research”

Section

Regular Articles

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