Electrochemical Hydrogen Peroxide Production in Acidic Medium Using a Tubular Photo-reactor: Application in Advanced Oxidation Processes
DOI:
https://doi.org/10.29356/jmcs.v58i3.144Keywords:
Electro-Fenton, Photoelecto-Fenton, Hydrogen peroxide, Photoelectrochemistry, Electrochemical reactor, DisinfectionAbstract
This paper describes the results obtained in the design and characterization of a tubular electrochemical reactor. The set-up was employed for on-site hydrogen peroxide (H2O2) production in an acidic medium (pH 3) to promote three electrochemical advanced oxidation processes (EAOP): electro-Fenton (EF), photoelectro-Fenton (PEF) and photocatalysis treatment (PT). These processes were evaluated by their abilities to degrade a commercial dye, Orange-II (OGII), in solution using total organic carbon (TOC) removal and high performance liquid chromatography (HPLC). To have free solutions of iron in the EF and PEF systems, a NafionTM membrane with dispersed iron was prepared. For use in photocatalysis, electrodes with a large superficial area were prepared by coating carbon cloth fiber supports with titanium dioxide (TiO2) using the electrophoretic (EP) method. In this work, wastewater samples with a large number of microorganisms (coliform bacteria) were treated with this new reactor design.
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