Efficient Synthesis of 12-Aryl-8,9,10,12-tetrahydrobenzo[a]-xanthen-11-ones using Ionic Liquid Pyrazinium Di(hydrogen sulfate) {Py(HSO4)2} as a Novel, Green and Homogeneous Catalyst

Authors

  • Abdolkarim Zare Payame Noor University
  • Roghayyeh Khanivar Payame Noor University
  • Marzieh Hatami Payame Noor University
  • Mohammad Mokhlesi Bu-Ali Sina University
  • Mohammad Ali Zolfigol Bu-Ali Sina University
  • Ahmad Reza Moosavi-Zare Sayyed Jamaloddin Asadabadi University
  • Alireza Hasaninejad Persian Gulf University
  • Ardeshir Khazaei Bu-Ali Sina University
  • Vahid Khakyzadeh Bu-Ali Sina University

DOI:

https://doi.org/10.29356/jmcs.v56i4.249

Keywords:

12-Aryl-8, 9, 10, 12-tetrahydrobenzo[a]-xanthen-11-one, pyrazinium di(hydrogen sulfate) {Py(HSO4)2}, protic acidic ionic liquid, homogeneous catalyst, one-pot multi-component reaction, solvent-free

Abstract

An efficient and simple solvent-free procedure for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]-xanthen-11-one derivatives via the one-pot multi-component condensation of dimedone with aromatic aldehydes and β-naphthol in the presence of protic acidic ionic liquid pyrazinium di(hydrogen sulfate) {Py(HSO4)2} as a green and homogeneous catalyst is described. All reactions proceed efficiently, and the title compounds are produced in high yields and in short reaction times.

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Author Biographies

Abdolkarim Zare, Payame Noor University

Department of Chemistry

Roghayyeh Khanivar, Payame Noor University

Department of Chemistry

Marzieh Hatami, Payame Noor University

Department of Chemistry

Mohammad Mokhlesi, Bu-Ali Sina University

Faculty of Chemistry

Mohammad Ali Zolfigol, Bu-Ali Sina University

Faculty of Chemistry

Ahmad Reza Moosavi-Zare, Sayyed Jamaloddin Asadabadi University

Department of Chemistry

Alireza Hasaninejad, Persian Gulf University

Department of Chemistry, Faculty of Sciences

Ardeshir Khazaei, Bu-Ali Sina University

Faculty of Chemistry

Vahid Khakyzadeh, Bu-Ali Sina University

Faculty of Chemistry

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Published

2017-10-12

Issue

Section

Regular Articles