Novel and Reusable Magnetic Zinc Ferrites Modified SBA-15 Supported Ionic Liquids for Sustainable and Efficient Cycloaddition of CO2 and Epoxides to Cyclic Carbonates
DOI:
https://doi.org/10.29356/jmcs.v68i3.1824Keywords:
Supported ionic liquid, magnetic zinc ferrites modified SBA-15, cycloaddition, cyclic carbonates, carbon dioxideAbstract
Abstract. A type of magnetic zinc ferrites modified SBA-15 supported ionic liquids have been synthesized and evaluated as effective catalysts for the synthesis of cyclic carbonates from epoxides and CO2. The effects of catalysts, CO2 pressure, reaction temperature, and catalyst stability have also been investigated, the catalyst ZnFe2O4@SBA-15-ILVO3 exhibited excellent activity in high to excellent yields (87~98 %) with excellent selectivities (98~99.7 %). Moreover, the catalyst exhibited excellent stability and could be easily recovered and reused for five times without a considerable decrease in catalytic activity. This work provides a sustainable and efficient strategy for the chemical fixation of carbon dioxide into valuable cyclic carbonates.
Resumen. Se sintetizó y evaluó un líquido iónico soportado tipo ferrita de zinc magnética modificada SBA-15 como un catalizador efectivo para la síntesis de carbonatos cíclicos a partir de epóxidos y CO2. Se investigaron los efectos del catalizador, el CO2, la presión, la temperatura de reacción y la estabilidad del catalizador; el catalizador ZnFe2O4@SBA-15-ILVO3 mostró una excelente actividad con rendimientos de altos a excelentes (87~98 %), así como excelentes selectividades. Adicionalmente, el catalizador mostró tener una excelente estabilidad, y se logró recuperar y reutilizar fácilmente en cinco ocasiones sin mostrar un decremento importante en su actividad catalítica. Este trabajo proporciona una estrategia sostenible y eficiente para la transformación química de dióxido de carbono en carbonatos cíclicos de alto valor.
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