Studies on Biologically Significant Copper (II) / Manganese (II) / Uranyl (II) – Isoleucine Binary Complexes
DOI:
https://doi.org/10.29356/jmcs.v52i3.1070Keywords:
paper ionophoresis, overall mobility, copper(II), manganese(II), uranyl(II), stability constants, isoleucineAbstract
The stability constants of Cu2+, Mn2+ and UO22+ complexes with isoleucine were determined by paper electrophoretic technique. Present method is based upon the migration of a spot of the metal ions on a paper strip at different pH’s of background electrolyte. A graph of pH against mobility gives information about the binary complexes and permit to calculate their stability constants. The first and second stability constants of [Cu(II) – isoleucine], [Mn(II) – isoleucine] and [UO2(II) – isoleucine] complexes were found to be (8.41 ± 0.07; 6.43 ± 0.03), (3.87 ± 0.11; 2.61 ± 0.06) and (7.91 ± 0.13; 5.73 ± 0.04) for Cu(II), Mn(II) and UO2(II) complexes, respectively at ionic strength 0.1 Mol/L and a temperature of 35 0C
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4. Guan, G.; Todo, T.; Tanaka, M.; Young, G.; Nagahama, Y. PNAS 2000, 97 (7), 3079-3083.
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7. Kawabe, M.; Sano, M.; Hagiwara, A.; Tamao, S.; Suzuki, S.; Shirai, T. Food Chem. Toxicol. 2006, 44(2), 278-285.
8. Schadewaldt, P.; Bodner-Leidecker, A.; Hammen, H. –W.; Wendel, U. Clinical Chem. 1999, 45, 1734-1740.
9. Xu, H.; Zhang, Y.; Guo, X.; Zhao, G. J. Bacteriol. 2004, 186 (16), 5400-5409.
10. Banerjea, D. Everyman’s Sci. 1995, 29(6), 176-184.
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12. Podunavac – Kuzmanovic, S. O.; Markov, S. L.; Vojinovic, L. S. APTEFF, 2004, 35, 247-254.
13. Zhang, F.; Yajima, T.; Masuda, H.; Odani, A.; Yamauchi, O. Inorg. Chem., 1997, 36 (25), 5777-5784.
14. Alpoguz, H.K.; Kaya, A.; Karacus, M. Turk J. Chem. 2005, 29, 345-353.
15. Kumar, G.; Kiremire, E. M. R. Chemistry 2007, 16 (5), 386-391.
16. Bauerova, K.; Valentova, J.; Ponist, S.; Navarova, J.; Komendova, D.; Mihalava, D. Biologia Bratislava, 2005, 60(17), 65-68.
17 Kisseleva, N.; Khvorova, A.; Westhof, E.; Schiemann, O. RNA 2005, 11, 1-6.
18 Baffert, C.; Collomb, M. –N.; Deronzier, A.; Thorup, N. Dalton Trans. 2003, 1765-1772.
19. Liu, S. B.; Perera, L.; Pedersen, L. G. Molecular Phys. 2007, 105, 2893- 2898.
20. Zhu, Q. –Y.; Dia, J.; Jia, D. –X.; GaO, L. –H.; Lin, H. –H. Eur. J. Inorg. Chem. 2004, 24, 4789-4794.
21. Qu, P.; Ji, R. –C.; Kato, S. Pancreas 2005, 31 (2), 148-155.
22. Shetty, V.; Hussaini, S.; Alvi, S.; Joshi, L.; Raza, A. Br. J. Haematol. 2002, 116(4-II), 817-825
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24. Romanenko, A. S.; Kovtun, G. Yu.; Salyaev, R. K. Ann. Bot. 1986, 57, 1-10.
25. Anderson, J. L.; Spitz, H. B.; Yiin, J. H. Health Phys. 2007, 93(6), 636-644.
26. Shaw, D. J. Electrophoresis, Academic Press, London, 1969, 99-103.
27. Tewari, B. B. Russ, J. Coord. Chem. 2003, 29, 441 – 444.
28. Tewari, B. B. Rev. Inorg. Chem. 1996, 16, 91-100.
29. Tewari, B. B.; Singh, R. K. P.; Kamaluddin; Yadava, K. L. Trans. SAEST, 1990, 25, 124-127.
30. Tewari, B. B., Singh R. K. P.; Yadava, K. L. J. Chromatogr. 1991, 542, 537-544.
31. Martell, A. E.; Smith, R. M. Critical Stability Constants, Vol. 1, Amino Acids, Plenum Press, New York, London, 1974, P. 12
32. Joshi, J. D.; Bhattacharya, P. K. J. Indian Chem. Soc. 1980, 57, 336-339.
33 Sillen, L. G.; Martell, A. E. Stability Constants of Metal Ion Complexes, Special Publication No. 17, Chemical Society London, 1974, p. 464.
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2019-07-31
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