Comparing Photocatalytic Activity of ZnO and Nanospherical ZnO/Bentonite Catalyst: Preparation, Structural Characterization and their Photocatalytic Performances using Oxytetracycline Antibiotic in Aqueous Solution

Authors

  • Ali ?mran VA?ZO?ULLAR Mu?la S?tk? Koçman University

DOI:

https://doi.org/10.29356/jmcs.v62i1.578

Keywords:

Organic contaminants, Pharmaceuticals, Photo-enhanced toxicology, ZnO/Bentonite catalyst, HRMS analysis

Abstract

Photocatalytic degradation of Oxytetracycline (OTC) in aqueous solution was performed using pure ZnO and ZnO/Bent composites. Both catalysts were synthesized trough a simple one-step chemical precipitation method. The prepared samples were characterized using SEM-EDAX and XRD analysis. Due to the immobilization of ZnO nanospheres upon bentonite surface, 25.67 m2 g-1 of specific surface area was obtained for the ZnO/Bent which lower than the specific surface area of the raw bentonite (112.25 m2 g-1). ZnO/Bent catalyst showed the best photocatalytic performance than ZnO for OTC degradation under UV light.

Downloads

Download data is not yet available.

Author Biography

Ali ?mran VA?ZO?ULLAR, Mu?la S?tk? Koçman University

Vocational School Health Care, Medical Laboratory Programme

References

Chen, M.; Chu, W. J. Hazard. Mater. 2012, 219, 183.

Palominoss, R.; Freer, J.; Mondaca, M.A.; Mansilla, H.D. J. Photoch. Photobio. A, 2008, 193, 139.

Batt, A.L.; Bruce, I.B.; Aga, D.S. Environ. Pollut 2006, 142, 295.

Xu, W.H.; Zou, S.C,, Li, X.D.; Liu, Y.C. Environ. Pollut, 2007, 145, 672.

Fatimah, I.; Wang, S.; Wulari, D. Appl. Clay. Sci 2011, 53, 553.

Borghi, A. A.; Palma, M. S. A. Braz. J.Pharm. Sci. 2014, 50(1), 25.

Hämäläinen, E.; Korpela, J. T.; Adlercreutz, H. Gut 1987, 28(4), 439.

Lin, J.; Wang, D.; Chen, D.; Ge, Q.; Ping, G.; Fan, M.; Qin, L.; Shu, K. Environ. Prog.Sustain. Energ 2015, 34,1.

Fang, L.; Zhang, B.; Li, W.; Li, X.; Xin, T.; Zhang, Superlattices and Microstructures 2014, , 324.

Abollino, O.; Giacomino, A.; Malrino, M.; Mentasti, E. Appl. Clay Sci 2008, 227.

Bhattacharyya, K.G.; Gupta, S.S. Adv. Colloid Interf. Sci 2008, 140, 114.

U?urlu, M, Karao?lu, M.H. Chem. Eng. J ,2011, 166, 859.

Meshram, S.; Limaye, R.; Ghodkec, S.; Nigama, S.; Sonawanea, S.; Chikate, R. Chem. Eng. J, 172, 1008.

Zhang, S.; Yang, J.; Xin, X.; Yan, L.; Wei, Q.; Du, B. Environ. Prog. Sustain. Energ 2015, 34, 39.

Zhang, A.; Zhang, R.; Zhang, N.; Hong, S.; Zhang, M. Kinet. Catal 2010, 51, 529.

Meng, X.; Qian, Z.; Wang, H.; Gao, X.; Zhang, S.; Yang, E.M. J. Sol. Gel. Sci. Technol 2008, 46, 195.

Soltani, R.D.C.; Jorfi, S.; Safari, M.; Rajaei, M.S. J. Environ. Manage 2016, 179, 47.

Khataee, A.; Soltani, R.D.C.; Karimi, A.; Joo, S.W. Ultrason. Sonochem 2015, 23, 219.

Kocí, K.; Matejka, V.; Kovar, P.; Lacný, Z.; Obalova, L. Catal. Today 2011, 161, 105.

Guo, Y.; Gong, Z.; Li, P.; Zhang, W.; Ga, B. Ceram. Int 2016, 42, 8850.

Sánchez-De la Torre, F.; la Rosa, D.; Rivera, J.; Kharisov, B. I.;Lucio-Ortiz, C. J. Materials 2013, 6(10), 4324.

Zhi, Y.; Li, Y.; Zhang, Q.; Wang, H. Langmuir 2010, 19,15546.

Fern´ez, L.; Garro, N.; El Haskouri, J.; Pe´rez-Cabero, M.; ? lvarez-Rodr guez, J.; Latorre, J.; Guillem, C.; Beltr, A.; Amor´os, P. Nanotechnology 2008,19, 225.

Han, J.; Hu, S.P.; Wang, Y.; Ma, J.J. J. Chem. Soc. Pak 2013, 35, 11.

Liu, Y.; He, X.; Duan, X.; Fu, Y.; Dionysios, D.D. Chem. Eng. J 2015, 276,113.

Lin, J.; Wang, D.; Chen, D.; Ge, Q.; Ping, G.; Fan, M.; Qin, L.; Shu, K. Environ. Prog. Sustain. Energ 2015, 34, 74.

Omar, F.M.; Aziz, H.A.; Stoll, S. J. Colloid Sci. Biotech 2014, 3, 1.

He, X.; Mezyk, S.P.; Michael, I.; Fatta-Kassinos, D.; Dionysiou, DD. J. Hazard. Mater 2014, 279, 375.

Pereira, J.H.O.S.; Vilar, V.J.P.; Borges, M.T.; Gonza´lez, O.; Esplugas, S.; Boaventura, R.A.R. Solar Energ 2011, 85, 2732.

Kanakaraju, D.; Motti, C.A.; Glass, B.D.; Oelgemo?ller, M. Chemosphere 2015, 139, 579.

Gan, H.; Zhang, G.; Huang, H. J.Hazard. Mater 2013, 250–251, 131.

Shaojun, J. I. A. O.; Zheng, S.; Daqiang, Y. I. N.; Lianhong, W. A. N. G.; Liangyan, C. H. E. N. Journal of Environmental Sciences, 2008, 20(7), 806.

Priya, B.; Shandilya, P.; Raizada, P.; Thakur, P.; Singh, N.; Singh, P. Journal of Molecular Catalysis A: Chemical 2016, 423, 400.

Sherly, E.D.; Vijaya, J.J.; Kennedy, L.J. Chinese J. Catal 2015, 36, 1263.

Hadjltaief, H. B., Zina, M. B., Galvez, M. E., & Da Costa, P. 2016 J. Photochem. Photobiol., A 315, 25.

Downloads

Published

2018-05-25

Issue

Section

Regular Articles