Synthesis of Monomeric and Dimeric Siloxanes Derived of β-Aminoalcohols
DOI:
https://doi.org/10.29356/jmcs.v51i1.1332Keywords:
Siloxanes, 29Si NMR, X-ray crystallography, aminoalcoholsAbstract
Abstract. The preparation and structural characterization of dimeric and monomeric siloxanes are described. The silicon complexes were obtained from β-amino alcohols and dichlorodimethylsilane, bisdimethylaminodimethylsilane and diphenyldichlorosilane. The complexes were characterized by 1H, 13C and 29Si NMR spectroscopy and mass spectrometry. The X-ray crystallography study for one compound confirmed the formation of a sixteen-membered heterocycle.
Resumen. En este trabajo se describe la preparación y la caracterización de siloxanos diméricos y monoméricos. Los complejos de silicio se obtuvieron por reacción de β-amino alcoholes con diclorodimetilsilano, bisdimetilaminodimetilsilano y diclorodifenilsilano. Los complejos se caracterizaron por RMN de 1H, 13C y 29Si, y espectrometría de masas. La estructura molecular de un anillo de 16 miembros para uno de los compuestos se confirmó por difracción de rayos-X.
Downloads
References
2. Tamao, K.; Hayashi, I., Y. Organometallics 1992, 11, 2099-2114.
3. Riggleman, S.; DeShong P. J. Org. Chem. 2003, 68, 8106-8109.
4. König, B.; Rödel, M., Bubenitschek, P.; Jones, P.G. Angew. Chem. Int. Ed. Engl. 1995, 34, 661-662.
5. Rezzonico, B.; Grignon-Dubois, M. Organometallics 1998, 17, 2656-2664.
6. Gómez, E.; Farfán, N. Heteroatom Chem. 1999, 10, 351-354.
7. Sekiguchi, A.; Yatabe, T.; Kabuto, C.; Sakurai, H. Angew. Chem. Int. Ed. Engl. 1989, 28, 757-758.
8. Nakanishi, K.; Mizuno, K.; Otsuji, Y. J. Chem Soc Perkin Trans 1. 1990, 12, 3362-3362.
9. Kira, M.; Tokura, S. Organometallics 1997, 16, 1100-1102.
10. Lee, C. W.; T. Hwang, G.; Kim, B. H. Tetrahedron Lett. 2000, 41, 4177-4180.
11. Jung, M. E.; Xia. H. Tetrahedron Lett. 1988, 29, 297-300.
12. Köing, B.; Rödel, M.; Bubenitschek, P. J. Org. Chem. 1995, 60, 7406-7410.
13. Gómez, E.; Santes, V.; de La Luz, V.; Farfán, N. J. Organomet. Chem. 1999, 590, 237-241
14. Gómez, E.; Santes, V.; de La Luz, V.; Farfán, N. J. Organomet. Chem. 2001, 622, 54-60.
15. Gómez, E.; Hernández, Z.; Álvarez, C.; Toscano, R. A.; Santes, V.; Sharma, P. J. Organomet. Chem, 2002, 648, 280-287.
16. Gómez, E. Recent Research Trends in Organomet. Chem., Ed. Research Signpost, India, 2005, 17-31
17. Voronkov, M.G. Pure Appl. Chem., 1996, 13, 35.
18. Gudat, D.; Verkade J. Organometallics, 1990, 9, 2172-2175.
19. Gudat, D.; Verkade, J. Organometallics, 1989, 8, 2772-2779.
20. Gudat, D.; Daniels, L.M.; Verkade, J.G. J. Am. Chem. Soc. 1989, 111, 8520-8522.
21. Chandrasekaran, A.; Day, R.O.; Holmes, R. R. J. Am. Chem. Soc. 2000,122, 1066-1072.
22. Kemme, A.; Bleidelis, J.; Urtane, I.; Zelchan, G.; Lukevicks, E. J. Organomet. Chem, 1980, 202, 115-121.
23. Liepins, E.; Popelis, J.; Brirgele, I.; Urtane, I.; Zelchan, G., Lukevicks, E. J. Organomet. Chem. 1980, 201, 113.
24. Kupce, E.; Liepins, E.; Lukevicks, E. J. Organomet. Chem. 1983, 248, 131-147.
25. Daly, J. J.; Sanz, F. J. Chem. Soc. Dalton Trans. 1974, 2051-2054.
26. Huerta, G.; Contreras G.; Alvarez C.; Toscano R.A.; Santes V.; Gómez E. Synthetic Comm. 2004, 34, 2393-2406.
27. Sheldrick, G.M., SHELXL 97 Program for refinement of crystal structures; University of Göttingen, Germany.
Downloads
Published
Issue
Section
License
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
