APTES-Functionalization of SBA-15 Using Ethanol or Toluene: Textural Characterization and Sorption Performance of Carbon Dioxide

Authors

  • Laura Munguía-Cortés Universidad Autónoma Metropolitana–Iztapalapa
  • Isaac Pérez-Hermosillo Universidad Autónoma Metropolitana–Iztapalapa
  • Reyna Ojeda-López Universidad Autónoma Metropolitana–Iztapalapa
  • Juan Marcos Esparza-Schulz Universidad Autónoma Metropolitana–Iztapalapa
  • Carlos Felipe-Mendoza Instituto Politécnico Nacional
  • Adrián Cervantes-Uribe Universidad Juárez Autónoma de Tabasco
  • Armando Domínguez-Ortiz Universidad Autónoma Metropolitana–Iztapalapa

DOI:

https://doi.org/10.29356/jmcs.v61i4.457

Keywords:

APTES, CO2 adsorption, functionalization, SBA-15, si-lanol ratio

Abstract

SBA-15 materials were functionalized with amino groups, APTES. The functionalization was carried out with ethanol or toluene, in air or nitrogen atmosphere. Texture and silanol ratio of functionalized materials were characterized by CO2 adsorption, N2 adsorption, SEM, TEM, and NMR. The results of this work indicates that functionalization in toluene is better than functionalization in ethanol, in order to anchor the largest number of APTES molecules on SBA-15 surface. For the same purpose, during functionalization process, the use of nitrogen atmosphere is better than the use of air atmosphere.

Downloads

Download data is not yet available.

Author Biographies

Laura Munguía-Cortés, Universidad Autónoma Metropolitana–Iztapalapa

Departamento de Química, Fisicoquímica de Superficies.

Isaac Pérez-Hermosillo, Universidad Autónoma Metropolitana–Iztapalapa

Departamento de Química, Fisicoquímica de Superficies.

Reyna Ojeda-López, Universidad Autónoma Metropolitana–Iztapalapa

Departamento de Química, Fisicoquímica de Superficies.

Juan Marcos Esparza-Schulz, Universidad Autónoma Metropolitana–Iztapalapa

Departamento de Química, Fisicoquímica de Superficies.

Carlos Felipe-Mendoza, Instituto Politécnico Nacional

Departamento de Biociencias e Ingeniería, CIIEMAD.

Adrián Cervantes-Uribe, Universidad Juárez Autónoma de Tabasco

División Académica de Ciencias Básicas, DACB.

Armando Domínguez-Ortiz, Universidad Autónoma Metropolitana–Iztapalapa

Departamento de Química, Fisicoquímica de Superficies.

References

Zhao, D.; Huo, Q.; Feng, J.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120 (24), 6024–6036.

Zhao, D.; Sun, J.; Li, Q.; Stucky, G. D.; Barbara, S. Chem. Mater 2000, 12, 275–279.

Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279 (5350), 548–552.

Liu, Y.; Lee, J. Y.; Hong, L. Journal of Power Sources 2002, 109, 507–514.

Wang, X. L.; Mei, A.; Li, M.; Lin, Y.; Nan, C. W. Solid State Ionics 2006, 177 (15–16), 1287–1291.

Sanz, R.; Calleja, G.; Arencibia, A.; Sanz-Perez, E. S. J. Mater. Chem. A 2013, 1 (6), 1956–1962.

Calleja, G.; Sanz, R.; Arencibia, A.; Sanz-Pérez, E. S. Top. Catal. 2011, 54, 135–145.

Wei, Y.; Li, X.; Zhang, R.; Liu, Y.; Wang, W.; Ling, Y.; Mohamed, A.; Zhao, D. Nat. Publ. Gr. 2016, No. January, 1–11.

Wang, L.; Ma, L.; Wang, A.; Liu, Q.; Zhang, T. Chinese J. Catal. 2007, 28 (9), 805–810.

Liu, X.; Zhou, L.; Fu, X.; Sun, Y.; Su, W.; Zhou, Y. Chemical Engineering Science 2007, 62, 1101–1110.

Kim, S. N.; Son, W. J.; Choi, J. S.; Ahn, W. S. Microporous Mesoporous Mater 2008, 115 (3), 497–503.

Hiyoshi, N.; Yogo, K.; Yashima, T. Microporous Mesoporous Mater 2005, 84 (1–3), 357–365.

Ryoo, R.; Ko, C. H.; Kruk, M.; Antochshuk, V.; Jaroniec, M. J. Phys. Chem. B 2000, 104 (48), 11465–11471.

Thielemann, J.; Girgsdies, F.; Schlögl, R.; Hess, C. Beilstein J. Nanotechnol. 2011, 2 (1), 110–118.

Ojeda-López, R.; Pérez-Hermosillo, I. J.; Esparza-Schulz, J. M.; Cervantes-Uribe, A.; Domínguez-Ortiz, A. Adsorption 2015, 21 (8), 659–669.

Ojeda-López, R.; Pérez-Hermosillo, I. J.; Esparza-Schulz, J. M.; Domínguez-Ortiz, A. Av. en Química 2014, 9 (1), 21–28. 17. Soler-Illia, G. J. a a; Azzaroni, O. Chem. Soc. Rev. 2011, 40 (2), 1107–1150.

Melero, J. a.; Stucky, G. D.; van Grieken, R.; Morales, G. Journal of Materials Chemistry 2002, pp 1664–1670.

Chong, A. S. M.; Zhao, X. S. J. Phys. Chem. B 2003, 107 (46), 12650–12657.

Sanz, R.; Calleja, G.; Arencibia, A.; Sanz-Pérez, E. S. Microporous Mesoporous Mater 2012, 158, 309–317.

Lombardo, M. V; Videla, M.; Calvo, A.; Requejo, F. G.; Soler-illia, G. J. A. A. J. Hazard. Mater. 2012, 223–224, 53–62.

Szegedi, A.; Popova, M.; Goshev, I.; Mihály, J. J. Solid State Chem. 2011, 184 (5), 1201–1207.

Moritz, M.; ?aniecki, M. Appl. Surf. Sci. 2012, 258 (19), 7523–7529.

Lombardo, M. V. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental. España. 2013.

Brunauer, S.; Emmett, P. H.; Teller, E. J. Am. Chem. Soc. 1938, 60 (1), 309–319.

Ravikovitch, P. I.; Neimark, A. V. J. Phys. Chem. B 2001, 105 (29), 6817–6823.

Thommes, M.; Kaneko, K.; Neimark, A. V.; Olivier, J. P.; Rodriguez-Reinoso, F.; Rouquerol, J.; Sing, K. S. W. Pure Appl. Chem. 2015, 87 (9–10), 1051–1069.

Pollock, R. A.; Walsh, B. R.; Fry, J.; Ghampson, I. T.; Melnichenko, Y. B.; Kaiser, H.; Pynn, R.; Desisto, W. J.; Wheeler, M. C.; Frederick, B. G. Chem. Mater 2011, 23 (17), 3828–3840.

Imperor-Clerc, M.; Davidson, P.; Davidson, A. J. Am. Chem. Soc. 2000, 122 (48), 11925–11933.

Galarneau, A.; Cambon, H.; Di Renzo, F.; Fajula, F. Langmuir 2001, 17 (26), 8328–8335.

Galarneau, A.; Cambon, H.; Di Renzo, F.; Ryoo, R.; Choi, M.; Fajula, F. New J. Chem. 2002, 27 (1), 73–79.

Savino, R.; Casadonte, F.; Terracciano, R. Molecules 2011, 16 (7), 5938–5962.

Ide, M.; El-Roz, M.; Canck, E. De; Vicente, A.; Planckaert, T.; Bogaerts, T.; Driessche, I. Van; Lynen, F.; Speybroeck, V. Van; Thybault-Starzyk, F.; Voort, P. Van Der. Phys. Chem. Chem. Phys. 2012, 15 (2), 642–650.

Wang, X.; Lin, K. S. K.; Chan, J. C. C.; Cheng, S. J. Phys. Chem. B 2005, 109 (5), 1763–1769.

Rahman, I. A.; Jafarzadeh, M.; Sipaut, C. S. Ceram. Int. 2009, 35 (5), 1883–1888.

Colilla, M.; Izquierdo-Barba, I.; Sánchez-Salcedo, S.; Fierro, J. L. G.; Hueso, J. L.; Vallet-Regí, M. Chem. Mater 2010, 22 (23), 6459–6466.

Wang, X.; Lin, K. S. K.; Chan, J. C. C.; Cheng, S. J. Phys. Chem. B 2005, 109 (5), 1763–1769.

Sanz-Pérez, E. S.; Olivares-Marín, M.; Arencibia, A.; Sanz, R.; Calleja, G.; Maroto-Valer, M. M. Int. J. Greenh. Gas Control 2013, 17, 366–375.

Knowles, G. P.; Graham, J. V; Delaney, S. W.; Chaffee, A. L. Fuel Processing Technology 2005, 86, 1435–1448.

Ünveren, E. E.; Monkul, B. Ö.; Sar?o?lan, ?.; Karademir, N.; Alper, E. Petroleum 2016, 1-14.

Vilarrasa-García, E.; Cecilia, J. A.; Santos, S. M. L.; Cavalcante, C. L.; Jiménez-Jiménez, J.; Azevedo, D. C. S.; Rodríguez-Castellón, E. Microporous Mesoporous Mater 2014, 187, 125–134.

Danon, A.; Stair, P. C.; Weitz, E. J. Phys. Chem. C 2011, 115 (23), 11540–11549.

Chang, A. C. C.; Chuang, S. S. C.; Gray, M.; Soong, Y. Energy & Fuels 2003, 17, 468–473.

Yuan, M. H.; Wang, L.; Yang, R. T. Langmuir 2014, 30 (27), 8124–8130.

Downloads

Published

2018-01-30

Issue

Vol. 61 No. 4 (2017): Regular Issue

Section

Regular Articles

License

Authors who publish with this journal agree to the following terms:

  • Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
  • Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.