Effect of CoMo/HSO3-functionalized MCM-41 over Heavy Oil

Authors

  • Persi Schacht Instituto Mexicano del Petróleo
  • Julia Aguilar-Pliego Universidad Autónoma Metropolitana Azcapotzalco
  • Marco Ramírez-Garnica Instituto Mexicano del Petróleo
  • Sergio Ramírez Instituto Mexicano del Petróleo
  • Ibrahim Abu University of Calgary
  • Luis Noreña-Franco Universidad Autónoma Metropolitana Azcapotzalco

DOI:

https://doi.org/10.29356/jmcs.v54i4.903

Keywords:

Functionalized MCM-41, Heavy Oil, HDS

Abstract

The potential of Co-Mo metals supported on functionalized MCM-41 as catalyst to hydrodesulfurization of heavy oil has been explored in this work. The MCM-41 functionalized sample was synthesized according to methods previously reported in the literature. Co and Mo metals were incorporated into the support by simultaneous impregnation. The catalyst was characterized by specific Surface area and X-Ray Diffraction. The pore channel of MCM-41 was confirmedby transmission electronic microscopy and infra red spectroscopy. Catalytic activity tests were carried out using heavy oil from Gulf of Mexico. The API gravity was increased from 12.5 to 20.2, the kinematics viscosity was decreased from 18,700 to 110 cSt at 298 K, the contents of asphaltene and sulfur were also reduced.

 

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Author Biography

Ibrahim Abu, University of Calgary

Department of Chemical & Petroleum Engineering

References

1. Hamilton, G.; Bhagava, L.; Louie, A. NPRA AM-94-7, 1994, 1-11.
2. Hammond, D.; Lampert, G. L.; Mart, F. C.; Massenzio, J.; Phillips, S. F.; Sellards, G. E.; Woerner, D. L. Sixth Topical Conference on Refining Processing Tutorial on Resid Upgrading; AIChE NPRA, 2003, 1-14.
3. Dominnici, V. E.; Sieli, G. M. Handbook of Petroleum Refining Processes, McGraw-Hill. 1997, 12-83.
4. Beaton, W. I.; Bertolacini, R. J. Catal.-Sci. Eng., 1991, 33 & 34, 281-371.
5. Morrison, M. E.; Stephens, G.; Billon, A.; Hennico, A.; Peries, J. P. Hyvahl-Solvahl. AM14963 Annual Meeting, San Antonio, Texas March, 1994, 20-22.
6. Colyar, J.J. Ebullated-Bed Reactor Technology, IFP Upgrading Heavy Ends Conference, Lyon, France, 1997, 25-26.
7. Lott, R.; Lee, K. T. SPE/PS-CIM/CHOA 98058, 2005, 1-9.
8. Meyers, R. A. Handbook of Petroleum Refining Processes, McGraw-Hill Companies, 1997, 10-15.
9. Meyers, R. A. Handbook of Petroleum Refining Processes, McGraw-Hill. 2004, 10-53.
10. Poddar, S. K.; Ragsdale, R.; Geosits, R. F.; Hood, R.; Lynch, L.; Rose, K.Z. NPRA, AM94-24, 1994, 1-20.
11. Speight, J.G. The Desulfurization of Heavy Oils and Residues, Marcel Dekker Inc., 2000, 188-193.
12. Leyva, C.; Rana, M.S.; Trejo F.; Ancheyta, J. Ind. Eng. Chem. Res. 2007, 46, 7448-7466.
13. Rahimi, P.; Gentzis, T.; Cotté, E. Energy Fuels 1999, 13, 694-701.
14. Nares, R.; Schacht, P.; Cabrera, C.; Ramírez, M.; Noé, L. JPT. 2007, 12, 49-50.
15. Kawi, S.; Shen, S. C. Mater. Lett. 2000. 42, 108-112.
16. Kawi, S.; Shen, S. C. Stud. Surf. Sci. Catal 2000, 129, 219-226.
17. Połtowicz, J.; Pamin, K.; Matachowski, L.; Serwicka, E.M.; Mokaya, R.; Xia, Y.; Olejniczak, Z. Catal. Today. 2006, 114, 287-292. Effect of CoMo/HSO3-functionalized MCM-41 over Heavy Oil 181
18. Mokaya, R. J. Phys. Chem. B. 2000, 104, 8279-8286.
19. Corma, A.; Fornés, V.; Navarro, M.T.; Pérez, J. J. Catal. 1994, 148, 569-574.
20. Kawi, S.; Shen S. C.; Chew, P. L. J. Mater. Chem. 2002, 12, 1582-1585.
21. Occelli, M.; Biz, L. S.; Auroux, A. Appl. Catal. A, 1999, 183, 231-239.
22. Beck, J. S. US Patent 5,057,296 1991.
23. Lee, J. S.; Rhee, C. H. Catal. Today. 1997, 38, 213-219.
24. Nongyue, H.; Zuhong, L.; Chunwei, Y.; Jianming, H.; Chun, Y.; Shulin, B.; Quinhua, X. Supramol. Sci. 1998, 5, 553-558.
25. Mokaya, R. Stud, Srf. Sc and Catal. 2007, 165, 123-126.
26. Gu, G.; Ong, P.; Chu, P. C. J. Phys. Chem. Solids. 1999, 60, 943-947.
27. Zhai, Q.; Wang, Z. P. J. Iran. Chem. Soc. 2008, 52, 68-273.
29. Caps, V.; Tsang, S. C. Appl. Catal. A: Gen. 2003, 248, 19-31.
30. Oliveira, P.; Machado, A.; Ramos, A. M.; Fonseca, I.; Braz Fernandes, F. M.; Botelho do Rego, A. M.; Vital, J. Micropor. Mesopor. Mater. 2009, 120, 432-440.
31. Alba, M. D.; Zhaohua Luan, Z.; Klinowski, J. J. Phys. Chem. 1996, 100, 2178-2182.
32. Fong, Y.; Zuhairi, Y. A.; Latif, A. A.; Bhatia, S. Micropor. Mesopor. Mater. 2009, 123, 129-139.
33. Ciesla, U.; Schüth, F. Micropor. Mesopor. Mater. 1999, 27, 131-149.
34. Kang, F.; Wang, Q.; Xiang, S. Mater. Lett. 2005, 59, 1426-1429.
35. Ancheyta, J.; Maity, S.; Betancourt, G.; Centeno, G.; Rayo, P.; Gómez, M. Appl. Catal. A. 2001, 216, 195-208.
35. Corma, A.; Kan, Q.; Navarro, M. T.; Pérez, J.; Rey, F. Chem. Mater. 1997, 9, 2123-2126.
36. Boveri, M.; Aguilar, J.; Perez, J.; Sastre, E. Catal. Today. 2005, 107, 868-873.
37. Schacht, P.; Noreña Franco, L.; Ancheyta, J.; Ramìrez, S.; Hernandez, I.; Garcıa L. A. Catal. Today. 2004, 98, 115-121.
38. Rhijin,W. M.; De Vos D. E.; Sels, B. F.; Bossaert, W. D.; Jacobs, P. A. Chem Commun. 1998, 4, 84-88.
39. Roman, M.; Gochi, Y.; Aguilar, A. Anuis do XX SICAT- Simpósio Ibero-Americano de Cátalise 2005, 1, 149-158.
40. Boveri, M.; Aguilar, J.; Márquez, C.; Pérez, J.; Sastre, E. Stud. Surf. Sc. Catal. 2005, 1558B, 1549-1556.
41. Nava, R.; Pawelec, B.; Morales, J. R.; Ortega, J.; Fierro, L. G. Micropor. Mesopor. Mat. 2009, 118, 189-201.

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Published

2019-06-05

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