Hydrophobic composite resins using a novel allylic urethane monomer as additive

Keywords: Allylic monomer, dental additive, dental composite, resins, photopolymerization

Abstract

The purpose of this study is to report the formulation of photopolymerizable composites resins with hydrophobic behavior using a new urethane monomer (ETODC) as additive. The ETODC monomer was used together with Bis-GMA and TEGDMA to formulate a new organic matrix system. Mechanical and hydrophobic behavior were studied, also volumetric shrinkage, viscosity, polymerization kinetics and cytotoxicity were analyzed. Results were compared with a control resin prepared with Bis-GMA and TEGDMA. The results show that mechanical properties and volumetric shrinkage did not present statistical differences between the studied groups. When compared with the control material, the experimental resin formulated with the ETODC monomer showed higher hydrophobic behavior and higher values of degree of conversion and polymerization rate.

Author Biographies

José Abraham González-López, Universidad Autónoma del Estado de Hidalgo

Doctorado en Ciencias de los Materiales

Alma Antonia Pérez-Mondragón, Universidad Autónoma del Estado de Hidalgo

Doctorado en Ciencias de los Materiales

Carlos E. Cuevas-Suárez, Universidad Autónoma del Estado de Hidalgo

Instituto de Ciencias de la Salud

Nayely Trejo-Carbajal, Universidad Autónoma del Estado de Hidalgo

Instituto de Ciencias Básicas e Ingeniería

Ana María Herrera-González, Universidad Autónoma del Estado de Hidalgo

Laboratorio de Polímeros, Instituto de Ciencias Básicas e Ingeniería.

References

Yin, M.; Liu, F.; He, J. J. Mech. Behav. Biomed. Mater. 2016, 57, 157-163.

Reinelt, S.; Tabatabai, M.; Moszner, N.; Fischer, U.K.; Utterodt, A.; Ritter, H. Macromol. Chem. Phys. 2014, 215, 1415-25.

Ferracane, J.L. Dent. Mater. 2011, 27, 29-38.

Chen, M-H. J. Dent. Res. 2010, 89, 549-560.

Moszner, N.; Hirt, T. J. Polym. Sci., Part A-1: Polym. Chem. 2012, 50, 4369-4402.

Peutzfeldt, A. Eur. J. Oral Sci. 1997, 105, 97-116.

Martim, G.C.; Pfeifer, C.S.; Girotto, E.M. Mater. Sci. Eng., C. 2017, 72, 192-201.

Martim, G.C.; Detomini, T.R.; Schuquel, I.T.; Radovanovic, E.; Pfeifer, C.S.; Girotto, E.M. Dent. Mater. 2014, 30, 155-163.

Khatri, C.A.; Stansbury, J.W.; Schultheisz, C.R.; Antonucci, J.M. Dent. Mater. 2003; 19: 584-588.

Stansbury, J.W. Dent. Mater. 2012, 28, 13-22.

Pereira, S.G.; Nunes, T.G.; Kalachandra, S. Biomaterials. 2002, 23, 3799-3806.

Ortiz, R.A.; Medina, L.A.R.; Duarte, M.L.B. J. Mater. Sci.: Mater. Med. 2013, 24, 2077-2084.

Eick, J.D.; Kotha, S.P.; Chappelow, C.C. Dent. Mater. 2007, 23, 1011-1017.

Moszner, N.; Gianasmidis, A.; Klapdohr, S.; Fischer, U.K.; Rheinberger, V. Dent. Mater. 2008, 24, 851-856.

Schneider, L.F.J.; Cavalcante, L.M.; Silikas, N.; Watts, D.C. J. Oral Sci. 2011, 53, 413-419.

Cruz-Aguilar, A.; Herrera-González, A.; Vázquez-García, R.; Navarro-Rodríguez, D.; Coreño, J. IOP Conference Series: Materials Science and Engineering. 2013, p. 012007.

González‐López, J.A., Cuevas‐Suárez, C.E.; Pérez‐Mondragón, A.A.; Berlanga, Duarte. M.L.; Herrera‐González. J. Appl. Polym. Sci. 2018, 135, 46240.

Herrera-González, A.M.; González-López, J.A; Cuevas-Suárez, C.E.; García-Castro, M.A.; Vargas-Ramírez, M. Polym. Compos. 2018, 39, E342-E350.

Herrera‐González ,M.A.; Cuevas‐Suárez, C.E.; Caldera‐Villalobos, M.; Pérez‐Mondragón, A.A. J. Appl. Polym. Sci. 2016, 133, 4.

Pérez-Mondragón, A.A.; Cuevas-Suárez, C.E.; Castillo, O.R.S.; González-López, J.A.; Herrera-González, A.M. Mater. Sci. Eng. C. 2018, 93, 80-87.

Cuevas-Suárez, C.E.; González-López, J.A.; da Silva, A.F.; Piva, E.; Herrera-González, A.M. J. Mech. Behav. Biomed. Mater. 2018, 87, 148-154.

Prakki, A.; Tallury, P.; Mondelli, R.F.L.; Kalachandra, S. Dent. Mat. 2007, 23, 1199-1204.

Fujisawa, S.; Atsumi, T.; Satoh, K. In Vitro Mol. Toxicol. 2000, 13, 269-280.

Denis, A.B.; Plepis, A.M.G.; Martins, Vd.C.A., Pereira, J.C.; Cilli, R., Prakki, A. Mater. Res. 2012, 15, 397-402.

Dental ANSIA and Association. ANSI/ADA Specification No. 27:1993 Resin-Based Filling Materials. 1993.

ISO E. 4049 Dentistry-Polymer-based filling, restorative and luting materials. International Organization for Standardization, Geneva, Switzerland. 1988.

British Standard B and ISO E. 17304: 2013. Dentistry–polymerization shrinkage: method for determination of polymerization shrinkage of polymer-based restorative materials Brussels, Belgium: International Standards Organisation. 2013.

Sideridou, I.; Tserki, V.; Papanastasiou, G. Biomaterials. 2002, 23, 1819-1829.

29. Neumann, M.G.; Miranda, Jr.W.G.; Schmitt, C.C.; Rueggeberg, F.A.; Correa, I.C. J. Dent.. 2005, 33, 525-532.

Cornelio, R.B.; Wikant, A.; Mjøsund, H. Acta Odontol. Scand. 2014, 72, 440-447.

Moszner, N.; Salz, U. Progress in polymer science. 2001, 26, 535-576.

Gonçalves, F.; Azevedo, C.L.; Ferracane, J.L.; Braga, R.R. Dent. Mater. 2011, 27, 520-526.

Published
12-09-2019