Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine
DOI:
https://doi.org/10.29356/jmcs.v55i3.815Keywords:
ABH, Coordination CompoundsAbstract
The present report is concerned with the synthesis and coordination compounds of 2-amino(N-aminobenzoyl)benzohydrazid e [ABH]. The ligand was characterized by proton NMR, mass spectrometry, elemental analysis, and infrared studies. The ligand has got —NH2 moiety which is capable of chelation. Therefore, complexes of Ni, Cu, and Zn (II) nitrates were prepared. These complexes were characterized by elemental analysis, infrared, conductance, and magnetic susceptibility studies. Infrared spectra showed that the ligand forms complexes through —NH2 moiety, while the elemental analysis suggest M(ABH)(NO3)2 composition of the coordination compounds, ABH acting as bidentate ligand.
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Martinez, J.; Martinez, A.; Cuenca, M. L.; Lopez, A. D. Synth. React. Inorg. Met. Org. Chem. 1988, 18, 881-901.
Ebd El Wahed, M. G.; Hassan, A.M.; Hammad, H. A.; El Desoky, M. M. B. Korean Chem. Soc. 1992, 13, 113-116.
Albertin, G.; Antoniutti, S.; Bordignon, E.; Chimisso, F. Inorg. Chem, Comm. 2001, 4, 402-404.
Gad, A. M.; Dissouky, A. E.; Mansour, E.M.; ElMaghraby, A. Polym. Degrad. Stabil. 2000, 68, 153-158.
Irving, H.; Rossotti, H. S. J. Chem. Soc. 1954, 2904-2910.
Abd El Wahed, M. G.; Metwally, S.; El Manakhly, K.; Hammad H. Can. J. Anal. Sci. Spec. 1998, 43, 37.
Redshaw, C.; Elsegood, M. R. J. Chem. Comm. 2006, 523-525.
Kost, D.; Kalikhman I. Acc. Chem. Res. 2009, 42, 303-314.
Hussain, M. S.; Rehman, S. U. Z. Naturforsch. 1978, 33b, 67-71.
Hussain, M. S.; Rehman S. U. Inorg. Chim. Acta 1982, 60, 231-238.
Rehman, S. U.; Noreen, S.; Rashida, I. M.; Ali, K.; Ahmad, I.; Arshad, M.; Bukhari, I. H. The Nucleus 2009, 46, 501-506.
Galal, S. A.; Hegab, K. H.; Kassab, A. S.; Rodriguez, M. L.; Kerwin, S. M.; El-Khamry, A. M. A.; Diwani, H. I. Eur. J. Med. Chem. 2009, 44, 1500-1508.
Chang R. Physical Chemistry for the Biosciences. University Science Books, Mill Valley, 2005, 482.
Roe, R. R.; Pang, Y.-P. J. Mol. Model. 1999, 5, 134-140.
Trzaskowski, B.; Adamowicz, L.; Deymier, P. A. J. Biol. Inorg. Chem. 2008, 13, 133.
Dudev, T.; Lim, C. J. Am. Chem. Soc. 2000, 122, 11146-11153.
Figgis, B. N., Lewis, J.; Wilkins, R. G., (Eds), Modern Coordination Chemistry. Interscience, New York, 1960, 412.
Vogel’s, Text Book of Quantitative Chemical Analysis. Longman Scientific and Technical Publishers, John Wiley & Sons, New York, 1989.
Friedman, L.; Litle, R. L.; Reichle, W. R. Org. Syn. Coll. 1973, 5, 1055.
Friedman, L.; Litle, R. L.; Reichle W. R. Org. Syn. 1960, 40, 93.
Chang, R. Physical Chemistry for the Biosciences. University Science Books, Mill Valley, 2005, 482.
Rehman, S. U.; Ikram, M.; Rehman, S. Front. Chem. China 2010,5, 348-356.
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