Evaluation of the Role of Matrix Matching for LA-ICP-MS Calibration Approaches in Quantitative Elemental Analysis of Tooth Enamel

Authors

  • Barbara Wagner Faculty of Chemistry, Biological and Chemical Research Centre, University of Warsaw
  • Olga Syta Faculty of Chemistry, Biological and Chemical Research Centre, University of Warsaw
  • Luiza K?pa Faculty of Chemistry, Biological and Chemical Research Centre, University of Warsaw
  • Ewa Bulska Faculty of Chemistry, Biological and Chemical Research Centre, University of Warsaw
  • Irena Segal Geological Survey of Israel, 30 Malkhe Israel St., Jerusalem, 95501, Israel
  • Ludwik Halicz a) Faculty of Chemistry, Biological and Chemical Research Centre, University of Warsaw, ?wirki I Wigury 101, 02-089 Warsaw, Poland b) Geological Survey of Israel, 30 Malkhe Israel St., Jerusalem, 95501, Israel

DOI:

https://doi.org/10.29356/jmcs.v62i2.410

Keywords:

LA-ICP-MS, matrix-matching, calibration

Abstract

A mineral apatite –based calibration approach for Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) was proposed in this work to be used for quantitative multielemental analysis of tooth enamel samples. Tooth enamel is composed mainly of hydroxyapatite therefore natural apatite crystals were expected to fit the matrix. Mineral samples were partially digested and quantitatively analyzed in respect of their bulk, elemental composition by means of ICP-MS/OES. The obtained quantitative data were used to construct the LA-ICP-MS calibration curves based on the apatite crystals for the selected 32 elements. The correlation coefficient values were calculated for each element and varied from none correlation for the most heterogeneous element (Al) to the value above 0.99 (U, REE, etc.), while calibration curve based on 3 selected mineral samples was applied. The usefulness of the proposed calibration approach was evaluated during investigations of elemental composition of tooth enamel and reference materials (NIST 1400, NIST 1486) leading to the promising results.

Downloads

Download data is not yet available.

References

Günther, D.; Jackson, S. E.; Longerich, H.P. Spectrochim. Acta B 1999, 54, 381-409 DOI: https://doi.org/10.1016/S0584-8547(99)00011-7

Russo, R. E.; Mao, X. L.; Liu, H. C.; Gonzalez, J.; Mao, S. S. Talanta 2002, 57, 425-451 DOI: https://doi.org/10.1016/S0039-9140(02)00053-X

Jochum, K. P.; Stoll, B.; Weis, U.; Jacob, D. E.; Mertz-Kraus, R.; Andreae, M. O. Geostand. Geoanal. Res. 2014, 38, 265-292 DOI: 10.1111/j.1751-908X.2014.12028.x

Jarvis, K. E.; Williams, J. G.; Chem. Geol. 1993, 106, 251-262, DOI: https://doi.org/10.1016/0009-2541(93)90030-M

Tang, M.; McDonough, W. F.; Arevalo, R. J. Anal. At. Spectrom. 2014, 29, 1835-1843, DOI: http://dx.doi.org/10.1039/C4JA00155A

Günther, D.; Quadt, A. V.; Wirz, R.; Cousin, H.; Dietrich, V. J. Mikrochim. Acta 2001, 136, 101-107, DOI: https://doi.org/10.1007/s006040170038

Pozebon, D.; Scheffler, G. L.; Dressler, V. L.; Nunes, M. A. G. J. Anal. At. Spectrom. 2014, 29, 2204-2228, DOI: http://dx.doi.org/10.1039/C4JA00250D

Urgast, D. S.; Feldmann, J. J. Anal. At. Spectrom. 2013, 28, 1367-1371, DOI: http://dx.doi.org/10.1039/C3JA50058F

Becker, J. S.; Zoriy, M.; Becker, J. S.; Dobrowolska, J.; Matusch, A. J. Anal. At. Spectrom. 2007, 22, 736-744, DOI: http://dx.doi.org/10.1039/B701558E

Giussani, B.; Monticelli, D.; Rampazzi, L. Anal. Chim. Acta 2009, 635, 6-21 DOI: 10.1016/j.aca.2008.12.040

Gruhl, S.; Witte, F.; Vogt, J.; Vogt, C. J. Anal. At. Spectrom. 2009, 24, 181-188, DOI: http://dx.doi.org/10.1039/B813734J

Pakie?a, M.; Wojciechowski, M.; Wagner, B.; Bulska, E. J. Anal. At. Spectrom. 2011, 26, 1539-1543, DOI: http://dx.doi.org/10.1039/C0JA00201A

Gilbert, S.; Danyushevsky, L.; Robinson, P.; Wohlgemuth-Ueberwasser, C.; Pearson, N.; Savard, D.; Norman, M.; Hanley, J. Geostand. Geoanal. Res. 2013, 37, 51–64 DOI: 10.1111/j.1751-908X.2012.00170.x

Ødegård, M.; Mansfeld, J.; Dundas, S. H. Fres. J. Anal. Chem. 2001, 370, 819–827 DOI: http://dx.doi.org/10.1039/B100899O

Kellett, L. C.; Golitko, M.; Bauer, B. S. J. Arch. Sc. 2013, 40, 1890-1902 DOI: https://doi.org/10.1016/j.jas.2012.11.014

Comodi, P.; Buccianti, A.; Zucchini, A.; Merletti, M.; Bergamini, M.; Nazzareni, S. Archeom. 2014, 56, 58-77 DOI: 10.1111/arcm.12068

Yong Sheng, L.; Zhao Chu, H.; Ming, L.; Shan, G. Chin. Sc. Bull. 2013, 58, 3863-3878 DOI: 10.1007/s11434-013-5901-4

Reiche, I.; Favre-Quattropani, L.; Calligaro, T.; Salomon, J.; Bocherens, H.; Charlet, L.; Menu, M. Nucl. Instr. Meth. Phys. Res. B 1999, 150, 656-662 DOI: https://doi.org/10.1016/S0168-583X(98)00949-5

McClellan, G.; Lehr, J. R. American Mineralogist 1969, 54, 1374-1379

Piccoli, P. M.; Candela, P. A., in: Phosphates: Geochemical, Geobiological, and Materials Importance, Kohn, M. J.; Rakovan, J.; Hughes J. M., 2002, 31, 255-292

Deer, W. A.; Chang, L. L. Y.; Howie, R. A.; Zussman, J. Rock-forming minerals, Ed. Geological Society, 1996

Kohn, M. J.; Schoeninger, M. J.; Barker, W. W. Geochim. Cosmochim. Acta 1999, 63, 2737-2747 DOI: https://doi.org/10.1016/S0016-7037(99)00208-2

Ghazi, A. M.; Shuttleworth, S.; Angulo, S. J.; Pashley, D. H J. Anal. At. Spectrom. 2000, 15, 1335-1341 DOI: http://dx.doi.org/10.1039/B001888K

Cucina, A.; Dudgeon, J.; Neff, H. J. Arch. Sc. 2007, 34, 1884-1888 DOI: https://doi.org/10.1016/j.jas.2007.01.004

Ugarte, A.; Unceta, N.; Pecheyran, C.; Goicolea, M. A.; Barrio, R. J. J. Anal. At. Spectrom. 2011, 26, 1421-1427 DOI: http://dx.doi.org/10.1039/C1JA10037H

Bellis, D. J.; Hetter, K. M.; Jones, J.; Amarasiriwardena, D.; Parsons, P. J. J. Anal. At. Spectrom. 2006, 21, 948-954 DOI: http://dx.doi.org/10.1039/B603435G

Govindaraju, K. Geostand. Newsl. 1994, 18, 331-331

http://georem.mpch-mainz.gwdg.de, accessed in July 2017

Gagnon, J. E.; Fryer, B. J.; Samson, I. M.; Williams-Jones, A. E. J. Anal. At. Spectrom. 2008, 23, 1529-1537 DOI: http://dx.doi.org/10.1039/B801807N

Halicz, L.; Günther, D. J. Anal. At. Spectrom. 2004, 19, 1539-1545 DOI: http://dx.doi.org/10.1039/B410132D

Liu, Y.; Hu, Z.; Gao, S.; Günther, D.; Xu, J.; Gao, C.; Chen, H. Chem. Geol. 2008, 257, 34-43 DOI: https://doi.org/10.1016/j.chemgeo.2008.08.004

Kempe, U.; Gotze, J. Mineral. Mag. 2002, 66, 151–172 DOI: 10.1180/0026461026610019

Downloads

Additional Files

Published

2018-06-06

Issue

Vol. 62 No. 2 (2018): Special Issue on “Modern Analytical Chemistry in Interdisciplinary Research”

Section

Regular Articles

License

Authors who publish with this journal agree to the following terms:

  • Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
  • Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
 

Similar Articles

You may also start an advanced similarity search for this article.