Studies on the Development of New Efficient Corrosion Inhibitors for Crude Oil Pipelines: Electrochemical Impedance Spectroscopy Results for 1,8-Naphthyridines

Authors

  • Rodolfo Álvarez-Manzo Instituto Mexicano del Petróleo
  • Joel Mendoza-Canales Instituto Mexicano del Petróleo
  • Salvador Castillo-Cervantes Instituto Mexicano del Petróleo
  • Jesús Marín-Cruz Instituto Mexicano del Petróleo

DOI:

https://doi.org/10.29356/jmcs.v57i1.234

Keywords:

1, 8-Naphthyridines, corrosion inhibitor, Friedländer synthesis, electrochemical impedance spectroscopy, inhibition efficiency

Abstract

Five 1,8-naphthyridines were tested as corrosion inhibitors, including three non-previously reported 3-alkyl-1,8-naphthyridines. All were produced via the extended Friedländer synthesis, that for 3-alkyl-1,8-naphthyridines involves the earliest use of aliphatic aldehydes. Fragmentation pattern in MS for 3-alkyl-1,8-naphthyridines shows a remarkable parallel with that exhibited by 3-alkylpyridines. Electrochemical Impedance Spectroscopy (EIS) was used to assess the inhibiting properties of these compounds on samples of API X52 carbon steel pipelines immersed in oilfield-related water. Except for one of the molecules tested, the inhibition  efficiency (IE%) values were significantly higher than that calculated for a reference commercial inhibitor.

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Published

2017-10-12

Issue

Section

Regular Articles

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