Effect of the Linker and Substituents on the Ionic Conductivity of Borate Single-Ion Polymers for Lithium Batteries
DOI:
https://doi.org/10.29356/jmcs.v68i4.2273Keywords:
Lithium-ion, Lithium-ion batteries, polymer electrolytes, ion transport, solid electrolyteAbstract
Polymer electrolytes with high ionic conductivity are actively searched for their application as solid electrolytes in lithium batteries. Here, we show new borate single lithium-ion conducting polymers with high ionic conductivity and lithium transference number values. For this purpose, eight new methacrylic lithium borate polymers were synthesized and characterized with varying chemical compositions focusing on the linker between the polymer chain and the pendant borate ionic group and its substituents. The polymers with the optimum ethoxy linker and fluorinated pendant groups show a low Tg value and the highest ionic conductivity value of 1.29×10-4 S.cm-1 at 60 °C. This value is among the highest ionic conductivity reported for a single lithium-ion conducting homopolymer. These polymers show a high lithium transference number (between 0.88 and 0.96) and electrochemical stability close to 4.2 V vs Li+/Li, making them promising candidates for application as solid electrolytes in lithium batteries.
Resumen. Se buscan activamente electrolitos poliméricos con alta conductividad iónica para su aplicación como electrolitos sólidos en baterías de litio. Aquí, mostramos nuevos polímeros conductores de iones de litio de borato simples con valores muy altos de conductividad iónica y número de transferencia de litio. Para ello, se sintetizaron y caracterizaron ocho nuevos polímeros metacrílicos de borato de litio con composiciones químicas variables centradas en el enlazador entre la cadena polimérica y el grupo iónico borato colgante y sus sustituyentes. Los polímeros con el enlazador etoxi óptimo y los grupos colgantes fluorados muestran un valor Tg bajo y un valor superior de conductividad iónica 1,29×10-4 Scm-1 a 60 °C. Este valor es uno de los más altos de conductividad iónica a 60 °C. Este valor es uno de los valores más altos de conductividad iónica a 60 °C. Este valor es uno de los más altos valores de conductividad iónica registrados para un solo homopolímero conductor de iones de litio. Estos polímeros muestran un elevado número de transferencia de litio (entre 0.88 y 0.96), y una estabilidad electroquímica cercana a 4.2 V vs Li+/Li que los convierten en candidatos prometedores para su aplicación como electrolitos sólidos en baterías de litio.
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Copyright (c) 2024 Soline Vauthier, Stéphane Cotte, Laurent Castro, Aurélie Guéguen, Nerea Casado, David Mecerreyes, Gregorio Guzman Gonzalez
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