Electrooxidation of Diclofenac in Synthetic Pharmaceutical Wastewater Using an Electrochemical Reactor Equipped with a Boron Doped Diamond Electrode

Authors

  • Gabriela Coria Universidad de Guanajuato
  • José L. Nava Universidad de Guanajuato
  • Gilberto Carreño Universidad de Guanajuato

DOI:

https://doi.org/10.29356/jmcs.v58i3.136

Keywords:

Degradation of diclofenac, boron doped diamond electrode, water treatment, electrooxidation, FM01-LC reactor

Abstract

This paper deals with the degradation of diclofenac by electrochemical oxidation in NaClO4 medium at neutral pH using a FM01-LC reactor equipped with a boron doped diamond electrode (BDD). Microelectrolysis studies were carried out to find the current density domain where hydroxyl radical (OH) formation is favored, 10 ≤ j ≤ 20 mA cm-2. Electrolysis experiments at mean linear flow velocities of 14.6 ≤ u ≤ 58.4 cm s-1 were performed. The experimental set-up achieved 100% diclofenac mineralization with 78% current efficiency and energy consumption of 2.54 kWh m-3 at j = 15 mA cm-2 and u=29.2 cm s-1.

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Author Biographies

Gabriela Coria, Universidad de Guanajuato

Departamento de Ingeniería Geomática e Hidráulica

José L. Nava, Universidad de Guanajuato

Departamento de Ingeniería Geomática e Hidráulica

Gilberto Carreño, Universidad de Guanajuato

Departamento de Ingeniería Geomática e Hidráulica

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Published

2017-10-12

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