Celite Catalysed Alkylation of Alkenes
DOI:
https://doi.org/10.29356/jmcs.v49i1.1314Keywords:
Celite, heterogeneous catalysis, electrophilic substitution, Friedel-Crafts}Abstract
Abstract. In the presence of Celite mono and disubstituted alkenes could be alkylated with benzylic halides at room temperature. In order to form the C-C bond, it was necessary to use activated aromatics with alkenes or propargylic esters.
Resumen. En presencia de celita, alquenos mono- y di-sistituidos pueden ser alquilados con halogenuros de bencilo a temperatura ambiente. Para formar el enlace C-C, fue necesario usar compuestos
aromáticos activados con alquenos o ésteres propargílicos.
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References
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2. Laszlo, P.; Vandormael, J. Chemistry Letters 1988, 1843-1846.
3. Rojas-Oviedo, I. Ph. D. Thesis, Medizinischen Universität zu Lübeck, Germany 1991.
4. Spange, S. Prog. Polym. Sci. 2000, 25, 781-849.
5. Neumüller, O. A. Rümps Chemie-Lexikon. Franckh´sche Verlagshandlung: Stuttgart, 1972, 522.
6. Toteva, M. M; Richard, J. P. J. Am. Chem. Soc. 1996, 118, 11434-11445.
7. Bauml, E.; Tscheschlok, K.; Pock, R.; Mayr, H. Tetrahedron Lett. 1988, 29, 6925-6926.
8. Mayr, H.; Striepe, W. J. Org. Chem. 1983, 48, 1159-1165.
9. van der Weerdt, A.J.; Cerfontain, H. Tetrahedron 1981, 37, 2121-2130.
10. Babler, J. H.; Tortorello, A. J. J. Org. Chem. 1976, 41, 885-887.
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2020-07-29
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