Comparative Studies on the Corrosion Inhibition of Three Different Organic Heterocyclic Compounds as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid

  • Zineb Tribak Sidi Mohamed Ben Abdellah University https://orcid.org/0000-0002-2169-9856
  • Mohammed Khalid Skalli Sidi Mohamed Ben Abdellah University
  • Amal Haoudi Sidi Mohamed Ben Abdellah University
  • Youssef Kandri Rodi Sidi Mohamed Ben Abdellah University
  • Omar Senhaji Moulay Ismaïl University
Keywords: Organic inhibitors, mild steel, corrosion, hydrochloric acid, the inhibition efficiency

Abstract

Abstract. Three organic inhibitors, based 5-Chloroisatin’s bases, namely, 1-allyl-5-chloro-indoline-2,3-dione (TZACI). 5-chloro-1-(2-(dimethylamino) ethyl) indoline-2,3-dione (TZCDI),5-chloro-1-octylindoline-2,3-dione (TZCOI) were influence on corrosion inhibition of mild steel in 1.0M hydrochloric acid solution. The inhibition efficiency increased with the increase of a compound concentration in the case of these three inhibitors, which have the mixed type behavior proposed by the polarization studies. Impedance measurements showed that after the addition of inhibitors, charge-transfer resistance increased and double-layer capacitance decreased, involving increased inhibition efficiency. The adsorption of three inhibitors on a steel surface obeyed Langmuir model. Free energy of adsorption showed that the type of adsorption was physical for TZACI and chemical for the TZCDI, TZCOI. Scanning electron microscopic analyses confirm the formation of the protective film on the surface.

Author Biographies

Zineb Tribak, Sidi Mohamed Ben Abdellah University

Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology

Mohammed Khalid Skalli, Sidi Mohamed Ben Abdellah University

Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology

Amal Haoudi, Sidi Mohamed Ben Abdellah University

Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology

Youssef Kandri Rodi, Sidi Mohamed Ben Abdellah University

Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology

Omar Senhaji, Moulay Ismaïl University

Laboratory of Applied Physical Chemistry, Faculty of Sciences and Technology of Errachidia

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Published
10-01-2020