Titanium-modified MCM-41 Prepared by Ultrasound and by Hydrothermal Treatment, Catalysts for Acetylation Reactions
DOI:
https://doi.org/10.29356/jmcs.v52i3.1064Keywords:
Ti-MCM-41, ultrasound technique, hydrothermal technique, mesoporous materials, acetylationAbstract
Mesoporous materials type Ti-MCM-41 prepared by hydrothermal and ultrasound-assisted techniques were characterized by XRD, SEM, TEM, nitrogen physisorption, ammonia TPD, UVvis and FT-IR. Both showed the MCM-41 characteristic structure. Hydrothermal treatment allowed obtaining a well ordered material and ultrasound procedure gave a better titanium distribution. Electronic microscopy images revealed Ti dispersion zones as well as the quantity of metal in the structure. The catalytic activity of these materials were tested by acetylation of aromatic and steroidal alcohols to afford the corresponding esters in good yields.
Downloads
Download data is not yet available.
References
1. Beck, J. S.; Vartulli, J. C.; Kennedy, G. J.; Kresge, C. T.; Schramm, W. J. Chem. Mater. 1994, 2, 1816-1821.
2. Corma, A. Chem. Rev. 1997, 97, 2373-2419.
3. Berlini, C.; Guidotti, M.; Moretti, G.; Psaro, R.; Ravasio, N. Catal. Today 2000, 60, 219-225.
4. Srinivas, D.; Srivastava, R.; Ratnasamy, P. Catal. Today 2004, 96, 127-133.
5. Corma, A.; Navarro, M. T.; Pérez-Pariente, J. J. Chem. Soc. Chem. Commun. 1994, 147-148.
6. Lu, Y.; Lu, G. Z.; Guo, Y. L.; Wang, Y. S. Cat. Commun. 2002, 3, 129-134.
7. A. Mohammed, A. D.; Stein, A. Chem. Mater. 2003, 15, 2638-2645.
8. Li, K. T.; Lin, C. C. Catal. Today 2004, 97, 257-261.
9. Laha, S. C.; Kumar, R. Mic. Mes. Mat. 2002, 53, 163-177.
10. a) Anunziata, O. A.; Beltramone, A. R.; Cussa, J. Appl. Catal. A: Gen. 2004, 270, 77-85. b) Ahn, W. S.; Lee, D. E.; Kim, T. H.; Seo, G.; Ryoo, R. Appl. Catal. 1999, 181, 39-49.
11. S. Suslick, K. S. Sience 1990, 247, 1439-1445.
12. Zhu, J.; Koltypin,Y.; Gedaken, A. Chem. Matter. 2000, 12, 73-78.
13. Suslik, K. MRS Bulletin, April 1995, 29-34.
14. Tang, X.; Liu, S.; Wang, Y.; Huang, W.; Sominski, E.; Palchik, O.; Kolltypin, Y.; Gedanken, A. Chem. Commun. 2000, 2119-2120.
15. Wang, Y.; Tang, X.; Yin, L.; Huang, W.; Rosenfeld, Y.; Gedanken, A. Adv. Mater. 2000, 12, 1183-1186.
16. Gedanken, A.; Tang, X.; Wang, Y.; Perkas, N.; Koltypin, Y.; Landau, M. V.; Vradman, L.; Herskowitz, M. Chem. Eur. J. 2001, 7, 4546-4552.
17. Perkas, N.; Wang, Y.; Koltypin, Y.; Gedanken, A.; Chandrasekaran, S. Chem. Commun. 2001, 988-989.
18. Thomas, J. M.; Terasaki, O.; Gai, P. L.; Zhou, W.; González- Calbet, J. Acc. Chem. Res. 2001, 34, 583-594.
19. a) Das, B.; Venkataiah, B.; Madhusudhan, P. Synth. Commun. 2002, 32, 249-252. b) Breton, G. W. J. Org. Chem. 1997, 62, 8952-8954. c) Martínez-Pascual, R.; Viñas-Bravo, O.; Meza- Reyes, S.; Iglesias-Arteaga, M. A.; Sandoval-Ramírez, J. Synth. Commun. 2004, 34, 4591-4596. d) Sandoval-Ramírez, J.; Castro-Méndez, A.; Meza-Reyes, S.; Reyes-Vázquez, S.; Santillán, R. L.; Farfán, N. Tetrahedron Lett. 1999, 40, 5143-5146. e) Sandoval- Ramírez, J.; Meza-Reyes, S.; Del Río, R. E.; Hernández-Linares, G.; Suárez-Rojas, A.; Rincón, S.; Farfán, N.; Santillán, R. L. Steroids 2003, 68, 199-204.
20. He, J.; Ma, H.; Guo, Z.; Evans, D. G.; Duan, X. Topics in catalysis. 2003, 22, 41-51.
21. Bhaumik, A.; Tatsumi, T. J. of Catal. 2000, 189, 31-39.
22. Chao, M. C.; Lin, H. P.; Mou, C. Y.; Cheng, B. W.; Cheng, C. G. Catal. Today 2004, 97, 81-87.
23. Alba, M. D.; Luan, A.; Klinowski, J. J. Phys. Chem. 1996, 100, 2178-2182.
24. Webb, P. A.; Orr, C. Analytical Methods in Fine Particle Technology. Micromeritics Instruments Corp. (Ga., USA, 1997).
25. Ángeles Beltrán, D.; Maubert Franco, A. M.; Lomas Romero, L.; Lara Corona, V. H.; Cárdenas, J.; Negrón Silva, G. J. Mex. Chem. Soc. 2003, 47, 155-159.
26. a) Hajipour, A. R.; Mazloumi G. Synth. Commun. 2002, 32, 23-30. b) Hossein, E.; Parvaneh, S. J. of Chem. Res. 2004, 12, 802-805. c) Tochtrop, G. P.; DeKoster, G. T.; Cistola, D. P.; Covey, D. F. Bio. & Med. Chem. Lett. 2002, 12, 433-435. c) Tochtrop, G. P.; DeKoster, G. T.; Cistola, D. P.; Covey, D. F. Bioorg. Med. Chem. Lett., 2002, 12, 433-435. d) Kantam, M. L.; Khathija, A.; Likhar P. R. Catal. Commun. 2006, 484–487. e) Khazaei, A.; Rostami, A.; Tanbakouchian, Z.; Zinati, Z. Catal. Commun. 2006, 7, 214–217. f) Kamal, A.; Khan, M. N. A.; Reddy, K. S.; Srikanth, Y. V. V.; Krishnaji, T. Tetrahedron Lett. 2007, 48, 3813–3818.
2. Corma, A. Chem. Rev. 1997, 97, 2373-2419.
3. Berlini, C.; Guidotti, M.; Moretti, G.; Psaro, R.; Ravasio, N. Catal. Today 2000, 60, 219-225.
4. Srinivas, D.; Srivastava, R.; Ratnasamy, P. Catal. Today 2004, 96, 127-133.
5. Corma, A.; Navarro, M. T.; Pérez-Pariente, J. J. Chem. Soc. Chem. Commun. 1994, 147-148.
6. Lu, Y.; Lu, G. Z.; Guo, Y. L.; Wang, Y. S. Cat. Commun. 2002, 3, 129-134.
7. A. Mohammed, A. D.; Stein, A. Chem. Mater. 2003, 15, 2638-2645.
8. Li, K. T.; Lin, C. C. Catal. Today 2004, 97, 257-261.
9. Laha, S. C.; Kumar, R. Mic. Mes. Mat. 2002, 53, 163-177.
10. a) Anunziata, O. A.; Beltramone, A. R.; Cussa, J. Appl. Catal. A: Gen. 2004, 270, 77-85. b) Ahn, W. S.; Lee, D. E.; Kim, T. H.; Seo, G.; Ryoo, R. Appl. Catal. 1999, 181, 39-49.
11. S. Suslick, K. S. Sience 1990, 247, 1439-1445.
12. Zhu, J.; Koltypin,Y.; Gedaken, A. Chem. Matter. 2000, 12, 73-78.
13. Suslik, K. MRS Bulletin, April 1995, 29-34.
14. Tang, X.; Liu, S.; Wang, Y.; Huang, W.; Sominski, E.; Palchik, O.; Kolltypin, Y.; Gedanken, A. Chem. Commun. 2000, 2119-2120.
15. Wang, Y.; Tang, X.; Yin, L.; Huang, W.; Rosenfeld, Y.; Gedanken, A. Adv. Mater. 2000, 12, 1183-1186.
16. Gedanken, A.; Tang, X.; Wang, Y.; Perkas, N.; Koltypin, Y.; Landau, M. V.; Vradman, L.; Herskowitz, M. Chem. Eur. J. 2001, 7, 4546-4552.
17. Perkas, N.; Wang, Y.; Koltypin, Y.; Gedanken, A.; Chandrasekaran, S. Chem. Commun. 2001, 988-989.
18. Thomas, J. M.; Terasaki, O.; Gai, P. L.; Zhou, W.; González- Calbet, J. Acc. Chem. Res. 2001, 34, 583-594.
19. a) Das, B.; Venkataiah, B.; Madhusudhan, P. Synth. Commun. 2002, 32, 249-252. b) Breton, G. W. J. Org. Chem. 1997, 62, 8952-8954. c) Martínez-Pascual, R.; Viñas-Bravo, O.; Meza- Reyes, S.; Iglesias-Arteaga, M. A.; Sandoval-Ramírez, J. Synth. Commun. 2004, 34, 4591-4596. d) Sandoval-Ramírez, J.; Castro-Méndez, A.; Meza-Reyes, S.; Reyes-Vázquez, S.; Santillán, R. L.; Farfán, N. Tetrahedron Lett. 1999, 40, 5143-5146. e) Sandoval- Ramírez, J.; Meza-Reyes, S.; Del Río, R. E.; Hernández-Linares, G.; Suárez-Rojas, A.; Rincón, S.; Farfán, N.; Santillán, R. L. Steroids 2003, 68, 199-204.
20. He, J.; Ma, H.; Guo, Z.; Evans, D. G.; Duan, X. Topics in catalysis. 2003, 22, 41-51.
21. Bhaumik, A.; Tatsumi, T. J. of Catal. 2000, 189, 31-39.
22. Chao, M. C.; Lin, H. P.; Mou, C. Y.; Cheng, B. W.; Cheng, C. G. Catal. Today 2004, 97, 81-87.
23. Alba, M. D.; Luan, A.; Klinowski, J. J. Phys. Chem. 1996, 100, 2178-2182.
24. Webb, P. A.; Orr, C. Analytical Methods in Fine Particle Technology. Micromeritics Instruments Corp. (Ga., USA, 1997).
25. Ángeles Beltrán, D.; Maubert Franco, A. M.; Lomas Romero, L.; Lara Corona, V. H.; Cárdenas, J.; Negrón Silva, G. J. Mex. Chem. Soc. 2003, 47, 155-159.
26. a) Hajipour, A. R.; Mazloumi G. Synth. Commun. 2002, 32, 23-30. b) Hossein, E.; Parvaneh, S. J. of Chem. Res. 2004, 12, 802-805. c) Tochtrop, G. P.; DeKoster, G. T.; Cistola, D. P.; Covey, D. F. Bio. & Med. Chem. Lett. 2002, 12, 433-435. c) Tochtrop, G. P.; DeKoster, G. T.; Cistola, D. P.; Covey, D. F. Bioorg. Med. Chem. Lett., 2002, 12, 433-435. d) Kantam, M. L.; Khathija, A.; Likhar P. R. Catal. Commun. 2006, 484–487. e) Khazaei, A.; Rostami, A.; Tanbakouchian, Z.; Zinati, Z. Catal. Commun. 2006, 7, 214–217. f) Kamal, A.; Khan, M. N. A.; Reddy, K. S.; Srikanth, Y. V. V.; Krishnaji, T. Tetrahedron Lett. 2007, 48, 3813–3818.
Downloads
Published
2019-07-31
Issue
Section
Regular Articles
License
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
