Bi and Three-Metallic Electrocatalysts Preparation for Methanol Oxidation
DOI:
https://doi.org/10.29356/jmcs.v52i1.1048Keywords:
electrochemical oxidation, methanol, Pt-Ru-Mo supported catalystAbstract
Bi and tri-metallic (Pt-Ru/C, Pt-Mo/C and Pt-Ru-Mo/C) catalysts were synthesized by using as precursors the metallic salts and applying the co-impregnation method. The tri-metallic catalysts underwent different thermal treatments and they were characterized by X-Ray. The catalytic activity for methanol oxidation reaction was determined by cyclic voltammetry (CV). The results show that the materials calcined before reduction presented the highest catalytic activity for methanol oxidation reaction.
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References
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6. Lima, A.; Coutanceau, C.; Léger, J.-M.; Lamy, C. J. Appl. Electrochem. 2001, 31, 379-386
7. Papageorgopoulos, D. C.; Keijzer, M.; Bruijn, F. A. Electrochimica Acta 2002, 48, 197-204
8. Shubina, T. E.; Koper, M. T. M. Electrochimica Acta. 2002, 47, 3621-3628
9. Gota, M.; Wendt, H. Electrochimica Acta. 1998, 43, 3637-3644
10. Guo, J. W.; Zhao, T. S.; Prabhuram, J.; Chen, R.; Wong C. W. Electrochimica Acta 2005, 51, 754-763
11. Santiago, E. I.; Camara, G. A.; Ticianelli, E. A. Electrochimica Acta 2003, 48, 3527-3534
12 Jeng, K. T.; Chien, C. C.; Hsu, N. Y.; Yen, S. C.; Chiou, S.-D.; Lin, S. H.; Huang, W. M. J. Power Sources 2006, 160, 97-104
13. Shao, Z.G.; Zhu, F.; Lin, W. F.; Christensen, P. A.; Zhang, H.; Yi, B. J. Electrochem. Soc. 2006, 153, A1575-A1583
14. Arico, A. S.; Baglio, V.; Di Blasi, A.; Modica, E.; Antonucci, P. L.; Antonucci V. J. Electroanal. Chem. 2003, 557, 167-176
15. Arico, A. S.; Baglio, V.; Di Blasi, A.; Modica, E.; Monforte, G.; Antonucci, V. J. Electroanal. Chem. 2005, 576, 161-169
16. Mao, Q.; Sun, G.; Wang, S.; Sun, H.; Wang, G.; Gao, Y.; Ye, A.; Tin, Y.; Xiu, Q. Electrochimica Acta 2007, 52, 6763-6770
17. Burstein, G. T.; Barnett, C. J.; Kucernak, A. R.; Williams, K. R. Catalysis Today. 1997, 38, 425-437
18. He, C.; Kunz, H. R.; Fenton, J. M. J. Electrochem. Soc. 1997, 144, 970-979
19. Azaroff, L. V. Elements of X-ray Crystallography, McGraw-Hill, New York, 1968
20. Park, K.-W.; Choi, J.-H.; Lee, S.-A.; Pak, C.; Chang, H.; Sung, Y.-E. J. of Catalysis. 2004, 224, 236-242
21. Mukerjee, S.; Urian, R. C. Electrochimica Acta 2002, 47, 3219-3231
22. Alerasool, S.; Boecker, D.; Rejai, B.; González, R.; Del ángel, G.; Asomoza, M.; Gómez R. Langmuir, 1988, 4, 1083-1090
23. Mukerjee, S.; Lee, S. J.; Ticianelli, E. A.; McBreen, J.; Grgur, B. N.; Markovic, N. M.; Ross, Jr. P. N.; Giallombardo, J. R.; De Castro, E. S. Electrochem. Solid-State Letters. 1999, 2 (1), 12-15
24. Gasteinger, H. A.; Markovic, N.; Ross, Jr. P. N.; Cairns, E. Electrochimica Acta 1994, 39, 1825-1832
25. Hammett, A. Mechanism of Methanol Electro-oxidationin “Intefacial Electrochemistry: Theory, Experiment, and Applications” (Wieckowski A., Ed.) p. 843, Dekker, New York, 1999
26. Watanabe, M.; Motoo, S. J. Electroanal. Chem., 1975, 60, 275-283
27. Gasteinger, H. A.; Markovic, N.; Ross, Jr. P. N.; Cairns, E. J. Phys. Chem. 1993, 97, 12020-12029
28. Santiago, E. I.; Batista, S. M.; Assaf, E. M. J. Electrochem. Soc. 2004, 151, 7, A944-A949
29. Ordóñez, L. C.; Roquero, P.; Sebastian P. J.; Ramírez, J. Catalysis Today. 2005, 107, 46-52
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2019-07-29
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