Oxidation of Some Organic Diols with Trialkylammonium Fluorochromates(VI), R3NH[CrO3F], (R= CH3, C2H5, C3H7 and C4H9) at Room Temperature and Under Microwave Condition

Authors

  • Shahriar Ghammamy Islamic Azad University; Faculty of Science
  • Samira Khorsandtabar Islamic Azad University
  • Ali Moghimi Islamic Azad University
  • Hajar Sahebalzamani Faculty of Science, Islamic Azad University

DOI:

https://doi.org/10.29356/jmcs.v53i2.1003

Keywords:

Trialkylammonium fluorochromates(VI), oxidants, oxidation, diols, microwave, room temperature

Abstract

A mild and efficient method for the mono-oxidation of diols to the corresponding hydroxyaldehydes with trialkylammonium fluorochromates(VI), R3NH[CrO3F] (R= CH3, C2H5, C3H7 and C4H9), in solution at room temperature, and in solution under microwave radiation, is reported. The easy procedure, simple work-up, short reaction times, and excellent yields are advantages of these reagents.

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Author Biographies

Shahriar Ghammamy, Islamic Azad University; Faculty of Science

Department of Chemistry; Department of Chemistry

Samira Khorsandtabar, Islamic Azad University

Department of Chemistry

Ali Moghimi, Islamic Azad University

Department of Chemistry

Hajar Sahebalzamani, Faculty of Science, Islamic Azad University

Departments of Chemistry

References

1. a) Bhandari, A.; Sharma, P. K.; Banerji, K. K. Indian J. Chem, 2001, 40A, 470-474 b) Ghammamy, S.; Moghimi, A.; Kohestani, B. Fluorine Notes J. 2008, 59.
2. O’Brien, B. A. Part I: Reactions of potassium dihydrogenphosphide and potassium diphenylphosphide with organic carbonyl compounds. Part II: Oxidation of primary and secondary alcohols by potassium chlorochromate( VI ). School of Chemistry and Biochemistry Thesis and Dissertations, Georgia Tech. 1980.
3. Littler, J. S. Tetrahedron 1971, 27, 81-91.
4. Trahanovsky, W. S.; Young, L. H.; Bierman, M. H. J. Org. Chem. 1969, 34, 869-871.
5. Yu, H.; Guo, F. Huaxue Shiji 2005, 27, 186.
6. Takahashi, N.; Katsuki, O. Decomposition of ethylene glycol by the combined use of ozone oxidation and electrolytic methods, Natl. Res. Inst. Pollut. Resour., Sukuba, Japan. Ozone: Science & Engineering, 1990, 12, 115-31.
7. Mohammadi, M. K.; Ghammamy, S.; Imanieh, H. Bull. Chem. Soc. Ethiop. 2008, 22, 449-452.
8. Seyedsajadi, S. A.; Ghammamy, S. Indian J. Chem. Sec. B, 2006, 45, 564-567.
9. Ghammamy, S.; Mazareey, M. J. Serb. Chem. Soc. 2005, 70, 687693.
10. Ghammamy, S.; Hashemzadeh, A. Bull. Korean Chem. Soc. 2004, 25, 1277-1279.
11. Meenahshisundaram, S.; Soctaungam, R. Collect. Czech. Chem. Commun., 2001, 66, 877-896.
12. Corey, E. J.; Boger, D. L. Tetrahedron Lett. 1978, 19, 2461-2464.
13. Corey, E. J.; Schmidt, G. Tetrahedron Lett. 1979, 20, 399-402.
14. Bhattacharjee, M. N.; Chaudhuri, M. K.; Dasgupta, H. S.; Roy, N. Synthesis 1982, 588-590.
15. Guziec, F. S.; Luzzio, F. A. Synthesis, 1980, 691-694.
16. Ghammamy, S.; Hashemzadeh, A. Bull. Korean Chem. Soc. 2004, 25, 1277-1279.
17. Mahjoub, A. R.; Ghammami, S.; Kassaee, M. Z. Tetrahedron Lett. 2003, 44, 4555- 4557.
18. akamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Third Edition, John Wiley & Sons: New York, 1978, Vol. 1 pp 140-150.

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Published

2019-06-24

Issue

Vol. 53 No. 2 (2009): Regular Issue

Section

Regular Articles

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