Thermogravimetric Study of Cracking Products of Natural Bitumens

Yerzhan Imanbayev, Yerdos Ongarbayev, Yerbol Tileuberdi, Evgenii Krivtsov, Anatoly Golovko Golovko, Zulkhair Mansurov

Abstract


The cracking and extraction products for Kazakhstan’s oil sand bitumen were determined by thermogravimetric analysis (TGA). By means of this technique, changes in the physical and chemical compositions of natural bitumen occurred during thermal treatment were assessed. The bulk composition was determined and the elemental content of resin-asphaltene compounds evaluated. Microspheres isolated from fly ash after the combustion of coals, were used to catalyze the cracking of natural bitumen. According to elemental analysis, natural bitumen is prone to produce coke formation. Catalytic cracking has a positive effect on the properties of the bitumen obtained from Munaily Mola field. The kinetic reaction orders and activation energies for cracking of natural bitumen were determined fitting the experimental data to an Arrhenius equation. The derived activation energies give insight on the nature of the pyrolysis kinetics of resin-asphaltene.

Keywords


Thermogravimetric analysis; natural bitumen; oil sand; cracking, activation energy.

Full Text:

PDF

References


Qing, W.; Chunxia, J.; Qianqian, J.; Yin, W.; Wu D. Fuel Processing Technology. 2012, 99, 110-114.

Ma, Y.; Li, Sh. Fuel Processing Technology. 2012, 100, 11-15.

Liu, P.; Zhu, M.; Zhang, Zh.; Wan, W.; Yani, S.; Zhang D. Energy Procedia. 2014, 61, 2741-2744.

Al-Otoom, A.; Al-Harahsheh, M.; Allawzi, M.; Kingman, S.; Robinson, J.; Al-Harahsheh, A.; Saeid A. Fuel Processing Technology. 2013, 106, 174-180.

Murugan, P.; Mahinpey, N.; Mani Th. Fuel Processing Technology. 2009, 90, 1286-129-1.

Ebrahimi, S.; Moghaddas, J.S.; Razavi Aghjeh M.K. Fuel. 2008, 87, 1623-1627.

Ongarbayev, Y.K.; Golovko, A.K.; Krivtsov, E.B.; Imanbayev, Y.I.; Tileuberdi, E.; Tuleutaev, B.; Mansurov Z.A. Solid Fuel Chemistry. 2016, 50, 81-87.

Murray R. Gray Upgrading Oilsands Bitumen and Heavy Oil, The University of Alberta Press, Alberta, 2015, 220-269.

Anshits, A.G.; Nizov, V.A.; Kondratenko, E.V. et al., Khim. Interesakh Ustoich. Razvit. 1999, 7, 105.

Sviridenko, N.N.; Krivtsov, E.B.; Golovko, A.K. Fundament. Issled. 2014, 8-4, 854.

Tileuberdi, Ye.; Mansurov, Z.; Ongarbayev, Ye.; Tuleutaev, B. Eurasian Chemico-Technological Journal. 2015, 17 (1), 41-45.

Sultanov, F.R.; Tileuberdi, Ye.; Ongarbayev, Ye.K.; Mansurov, Z.A.; Khaseinov, K.A.; Tuleutaev, B.K.; Behrendt, F.; Eurasian Chemico-Technological Journal. 2013, 15, 77-81.

Imanbayev, Ye.; Ongarbayev, Ye.; Tileuberdi, Ye.; Krivtsov, E.; Golovko, A.; Mansurov, Z.; Journal of the Serbian Chemical Society. 2017, 82 (9), 1063-1073.




DOI: http://dx.doi.org/10.29356/jmcs.v61i4.465

Refbacks

  • There are currently no refbacks.


Copyright (c) 2018 Yerzhan Imanbayev, Yerdos Ongarbayev, Yerbol Tileuberdi, Evgenii Krivtsov, Anatoly Golovko Golovko, Zulkhair Mansurov

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Journal of the Mexican Chemical Society (J. Mex. Chem. Soc.) Vol 61, No 4 (2017). Quarterly publication (October-December). Edited and distributed by Sociedad Química de México, A.C. Barranca del Muerto 26, Col. Crédito Constructor, Del. Benito Juárez, C.P. 03940, Mexico City. Phone: +5255 56626837; +5255 56626823 Contact: soquimex@sqm.org.mx http://www.sqm.org.mx Editor-in-Chief: Ignacio González-Martínez. Indexed Journal. Certificate of reserved rights granted by the Instituto Nacional del Derecho de Autor (INDAUTOR): 04-2005-052710530600-102. Certificate of lawful title and content: Under procedure. ISSN-e granted by the Instituto Nacional del Derecho de Autor (INDAUTOR): 2594-0317. ISSN granted by the Instituto Nacional del Derecho de Autor (INDAUTOR): 1870-249X. Postal registration of printed matter deposited by editors or agents granted by SEPOMEX: IM09-0312 Copyright © Sociedad Química de México, A.C. Total or partial reproduction is prohibited without written permission of the right holder. The Figures/schemes quality and the general contents of this publication are full responsibility of the authors. Updated April 24th, 2018 by Adriana Vázquez (editorial assistant, e-mail: editor.jmcs@gmail.com), J. Mex. Chem. Soc., Sociedad Química de México, A.C.