APTES-Functionalization of SBA-15 Using Ethanol or Toluene: Textural Characterization and Sorption Performance of Carbon Dioxide

Laura Munguía-Cortés, Isaac Pérez-Hermosillo, Reyna Ojeda-López, Juan Marcos Esparza-Schulz, Carlos Felipe-Mendoza, Adrián Cervantes-Uribe, Armando Domínguez-Ortiz

Abstract


SBA-15 materials were functionalized with amino groups, APTES. The functionalization was carried out with ethanol or toluene, in air or nitrogen atmosphere. Texture and silanol ratio of functionalized materials were characterized by CO2 adsorption, N2 adsorption, SEM, TEM, and NMR. The results of this work indicates that functionalization in toluene is better than functionalization in ethanol, in order to anchor the largest number of APTES molecules on SBA-15 surface. For the same purpose, during functionalization process, the use of nitrogen atmosphere is better than the use of air atmosphere.

Keywords


APTES; CO2 adsorption; functionalization; SBA-15; si-lanol ratio

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DOI: http://dx.doi.org/10.29356/jmcs.v61i4.457

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Journal of the Mexican Chemical Society (J. Mex. Chem. Soc.) Vol 62, No 2 (2018). Quarterly publication (April-June). Edited and distributed by Sociedad Química de México, A.C. Barranca del Muerto 26, Col. Crédito Constructor, Del. Benito Juárez, C.P. 03940, Mexico City. Phone: +5255 56626837; +5255 56626823 Contact: soquimex@sqm.org.mx http://www.sqm.org.mx Editor-in-Chief: Ignacio González-Martínez. Indexed Journal. Certificate of reserved rights granted by the Instituto Nacional del Derecho de Autor (INDAUTOR): 04-2005-052710530600-102. Certificate of lawful title and content: Under procedure. ISSN-e granted by the Instituto Nacional del Derecho de Autor (INDAUTOR): 2594-0317. ISSN granted by the Instituto Nacional del Derecho de Autor (INDAUTOR): 1870-249X. Postal registration of printed matter deposited by editors or agents granted by SEPOMEX: IM09-0312 Copyright © Sociedad Química de México, A.C. Total or partial reproduction is prohibited without written permission of the right holder. The Figures/schemes quality and the general contents of this publication are full responsibility of the authors. Updated June 6th, 2018 by Adriana Vázquez (editorial assistant, e-mail: editor.jmcs@gmail.com), J. Mex. Chem. Soc., Sociedad Química de México, A.C.